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American Mineralogist; February 1983; v. 68; no. 1-2; p. 11-17
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Modulated structures at phase transitions

Horst Boehm

Univ. Muenster, Inst. Mineral., Munster, Federal Republic of Germany

Characteristics of modulated structures which appear as intermediate phases between a high-symmetry high-temperature phase and a low-temperature phase of lower symmetry. Two examples: for NaNO 2 , previously published results are reviewed; for LiAlSiO 4 , the modulation of the structure is interpreted as being caused by the formation of domains which fluctuate in their width. This domain hypothesis is supported by model calculations.--Modified journal abstract.

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D. R. Veblen, J. F. Banfield, G. D. Guthrie Jr., P. J. Heaney, E. S. Ilton, K. J. T. Livi, and E. A. Smelik
High-Resolution and Analytical Transmission Electron Microscopy of Mineral Disorder and Reactions
Science, June 4, 1993; 260(5113): 1465 - 1472.
[Abstract] [PDF]


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