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American Mineralogist; August 1983; v. 68; no. 7-8; p. 731-741
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The extraction-quench technique for determination of the thermodynamic properties of solute complexes; application to quartz solubility in fluid mixtures

John V. Walther, and Philip M. Orville

Northwest. Univ., Dep. Geol. Sci., Evanston, IL, United States
Yale Univ., United States

Hydration state, charge and chemical stoichiometry, and Gibbs free energy of aqueous species.A hydrothermal apparatus, capable of obtaining the necessary solubility data in fluid mixtures, is described. Stoichiometry of the dominant aqueous silica species of Si(OH) 4 . 2H 2 O in the supercritical region of H 2 O. Prediction of silica concentrations in CO 2 -H 2 O mixtures in the system CaO-MgO-SiO 2 -HCl-CO 2 -H 2 O at 2 kbar and 450 degrees C.--Modified journal abstract.

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