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American Mineralogist; March 1999; v. 84; no. 3; p. 357-361
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Subsolidus and melting experiments of a K-rich basaltic composition to 27 GPa; implication for the behavior of potassium in the mantle

Wuyi Wang, and Eiichi Takahashi

Tokyo Institute of Technology, Department of Earth and Planetary Sciences, Tokyo, Japan

Subsolidus and melting experiments of a K-rich basaltic composition have been performed to 27 GPa. Pyroxene and majoritic garnet contain significant amounts of K 2 O (1-2 wt%) at 6-12.5 GPa and above 22.5 GPa, respectively. Both pyroxene and garnet may act as main reservoirs for K in the mantle. Sanidine (KAlSi 3 O 8 ) or its polymorph potassium hollandite is the first phase to be melted up to 20 GPa, but potassium hollandite becomes a liquidus phase at P> or =22.5 GPa. In contrast to its typical incompatible behavior at low pressures, potassium is a compatible element in the deep mantle, at least in basaltic systems. This compatible behavior implies that a K-rich melt like kimberlite is difficult to generate at lower mantle conditions.

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